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Formation de particules par séchage en gouttes : observation de l'évolution morphologique et mesure du diamètre aérodynamique

D. HARDY (1), J. WALKER (1), P. LEMAITRE (2), J. REID (1)

1. School of Chemistry, Univeristy of Bristol, Bristol, Royaume-Uni
2. PSN-RES, SCA, LPMA, IRSN, Gif-sur-Yvette, France

[2022]

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Résumé

In this article we study the influence of the drying kinetics of a droplet on the morphological characteristics of the particles produced, with the aim of modeling the aerodynamic properties of the aerosols thus formed.

We present the development of a new device making it possible to analyze in detail the evaporation of droplets, from their production to the formation of a dry particle, including the nucleation of the first crystals. This experiment makes it possible to study the evaporation of the drops with a temporal resolution lower than a microsecond, and thus to detect very precisely, by image analysis, the deduction of the crystallization. We present a first study carried out on an inorganic salt and which shows, depending on the drying conditions, a wide variety of particle morphologies.


Mots clés

séchage par atomisation, cristallisation, cinétique d'évaporation, morphologie

Abstract

An investigation into the relationship between factors governing droplet drying and resultant particle morphologies, with a specific interest in the aerodynamic properties of dried particles. This work describes a new Falling Droplet Column (FDC), which offers the capability to analyze in detail the entire evaporative lifetime of individual droplets, from generation to dry particle formation, with capability for sub-microsecond temporal resolution and subsequent offline analysis of dried particles by SEM. A comparison of evaporative profiles and resulting morphologies produced in a range of conditions for different inorganic salts is presented. We will explore the specific crystallization events through detailed imaging of aerosol droplets.


Keywords

spray drying, droplet crystallisation, evaporation kinetics, particle morphology

DOI

10.25576/ASFERA-CFA2022-28397

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